Determination of nitrites and nitrates in plasma-activated deionized water by microchip capillary electrophoresis
Corresponding Author
Ladislav Moravský
Department of Experimental Physics, Comenius University, Bratislava, Slovakia
Correspondence
Ladislav Moravský, Department of Experimental Physics, Comenius University, Mlynská dolina F2, 84248 Bratislava, Slovakia.
Email: wikingsbrummy@gmail.com
Search for more papers by this authorPeter Troška
Department of Analytical Chemistry, Comenius University, Bratislava, Slovakia
Search for more papers by this authorMatej Klas
Department of Experimental Physics, Comenius University, Bratislava, Slovakia
Search for more papers by this authorMarián Masár
Department of Analytical Chemistry, Comenius University, Bratislava, Slovakia
Search for more papers by this authorŠtefan Matejčík
Department of Experimental Physics, Comenius University, Bratislava, Slovakia
Search for more papers by this authorCorresponding Author
Ladislav Moravský
Department of Experimental Physics, Comenius University, Bratislava, Slovakia
Correspondence
Ladislav Moravský, Department of Experimental Physics, Comenius University, Mlynská dolina F2, 84248 Bratislava, Slovakia.
Email: wikingsbrummy@gmail.com
Search for more papers by this authorPeter Troška
Department of Analytical Chemistry, Comenius University, Bratislava, Slovakia
Search for more papers by this authorMatej Klas
Department of Experimental Physics, Comenius University, Bratislava, Slovakia
Search for more papers by this authorMarián Masár
Department of Analytical Chemistry, Comenius University, Bratislava, Slovakia
Search for more papers by this authorŠtefan Matejčík
Department of Experimental Physics, Comenius University, Bratislava, Slovakia
Search for more papers by this authorFunding information: Agentúra na Podporu Výskumu a Vývoja, APVV-0259-12; APVV-17-0318; Vedecká Grantová Agentúra MŠVVaŠ SR a SAV, VEGA 1/0733/17, VEGA 1/0787/18
Abstract
In this work, we present the application of a fast and sensitive microanalytical method, microchip capillary electrophoresis (MCE), for the determination of NO2− and NO3− ions in deionized water treated by atmospheric pressure plasma jet (APPJ). The MCE technique consisted of an online combination of isotachophoresis with zone electrophoresis, both performed on the microchip. The argon plasma has been characterized by optical emission spectroscopy (OES) and Fourier transform infrared spectroscopy (FTIR). OES confirmed the presence of argon excited species (Ar I) emission (4p → 4s) lines, N2 emission bands (second positive system C3Πu → B3Πg), and OH band (A2∑+ → X2Π Δv = 0), as well as the presence of NO and excited NO2. The presence of NO2 molecules was also confirmed by FTIR absorption spectroscopy. The performance of the developed MCE method was evaluated for linearity, limit of detection, limit of quantitation, precision, and accuracy, and the concentration of NO2− and NO3− in the water as a function of the water treatment time was monitored.
Supporting Information
Filename | Description |
---|---|
ctpp202000014-sup-0001-Supinfo.docxWord 2007 document , 16.8 KB |
Data S1. Water purification and MCE parameters |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
REFERENCES
- 1P. Sun, J. Pan, Y. Tian, N. Bai, H. Wu, L. Wang, C. Yu, J. Zhang, W. Zhu, K. H. Becker, J. Fang, IEEE Trans. Plasma Sci. 2010, 38, 1892.
- 2W. C. Trogler, Coord. Chem. Rev. 1999, 187, 303.
- 3A. Fridman, Plasma Chemistry, Cambridge University Press, New York 2008.
10.1017/CBO9780511546075 Google Scholar
- 4M. Cooper, G. Fridman, D. Staack, A. F. Gutsol, V. N. Vasilets, S. Anandan, Y. I. Cho, A. Fridman, A. Tsapin, IEEE Trans. Plasma Sci. 2009, 37, 866.
- 5M. H. Thiemens, W. C. Trogler, Science 1991, 251, 932.
- 6F. Judée, N. Merbahi, M. Yousfi, Plasma Med. 2016, 6, 15823.
- 7J. Chauvin, F. Judée, M. Yousfi, P. Vicendo, N. Merbahi, Sci. Rep. 2017, 7, 4562.
- 8M. Keidar, A. Shashurin, O. Volotskova, M. A. Stepp, P. Srinivasan, A. Sandler, B. Trink, Phys. Plasmas 2013, 20, 057101.
- 9N. Kaushik, N. Kumar, C. H. Kim, N. Kaushik, E. H. Choi, Plasma Processes Polym. 2014, 11, 1175.
- 10F. Judée, C. Fongia, B. Ducommun, M. Yousfi, V. Lobjois, N. Merbahi, Sci. Rep. 2016, 6, 21421.
- 11T. Adachi, H. Tanaka, S. Nonomura, H. Hara, S. Kondo, M. Hori, Free Radic. Biol. Med. 2015, 79, 28.
- 12A. M. Hirst, M. S. Simms, V. M. Mann, N. J. Maitland, D. O'Connell, F. M. Frame, Br. J. Cancer 2015, 112, 1536.
- 13F. Utsumi, H. Kajiyama, K. Nakamura, H. Tanaka, M. Hori, F. Kikkawa, Springer Plus 2014, 3, 398.
- 14J.-M. Plewa, M. Yousfi, C. Frongia, O. Eichwald, B. Ducommun, N. Merbahi, V. Lobjois, New J. Phys. 2014, 16, 043027.
- 15H. Uchiyama, Q. L. Zhao, M. A. Hassan, G. Andocs, N. Nojima, K. Takeda, K. Ishikawa, M. Hori, T. Kondo, PLoS One 2015, 10, e0136956.
- 16M. Sahni, B. R. Locke, Ind. Eng. Chem. Res. 2006, 45, 5819.
- 17M. Tahara, M. Okubo, J. Electrostat. 2014, 72, 222.
- 18S. Kanazawa, T. Furuki, T. Nakaji, S. Akamine, R. Ichiki, Int. J. Plasma Environ. Sci. Technol. 2012, 6, 166.
- 19B. R. Locke, M. Sato, P. Sunka, M. R. Hoffmann, J.-S. Chang, Ind. Eng. Chem. Res. 2006, 45(3).
- 20S. Reuter, J. Winter, A. Schmidt-Bleker, D. Schroeder, H. Lange, N. Knake, V. S.-v. der Gathen, K.-D. Weltmann, Plasma Sources Sci. Technol. 2012, 21, 024005.
- 21C. A. Davies, D. Perrett, Z. Zhang, B. R. Nielsen, D. R. Blake, P. G. Winyard, Electrophoresis 1999, 20, 2111.
10.1002/(SICI)1522-2683(19990701)20:10<2111::AID-ELPS2111>3.0.CO;2-5 CASPubMedWeb of Science®Google Scholar
- 22A. A. Okemgbo, H. H. Hill Jr., W. F. Siems, S. G. Metcalf, Anal. Chem. 1999, 71, 2725.
- 23F. Tagliaro, F. Bortolotti, G. Manetto, V. L. Pascali, M. Marigo, Electrophoresis 2002, 23, 278.
- 24J. M. Monaghan, K. Cook, D. Gara, D. Crowther, J. Chromatogr. A 1997, 770, 143.
- 25D. Y. Boudko, B. Y. Cooper, W. R. Harvey, L. L. Moroz, J. Chromatgr. B 2002, 774, 97.
- 26F. Guan, H. Wu, Y. Luo, J. Chromatogr. A 1996, 719, 427.
- 27D. Kaniansky, V. Zelenska, D. Baluchova, Electrophoresis 1996, 17, 1890.
- 28E. Martínková, T. Křžek, P. Coufal, Chem. Pap. 2014, 68, 1008.
- 29M. R. Baezzat, G. Parsaeian, M. A. Zare, Quim. Nova 2011, 34(4), 607.
- 30B. Narayana, K. Sunil, Eurasian J. Anal. Chem. 2009, 4(2), 204.
- 31S. Gajaraj, C. Fan, M. Lin, Z. Hu, Environ. Monit. Assess. 2013, 185, 5673.
- 32 G. Horváth, L. Moravský, F. Krčma, Š. Matejčík, IEEE Trans. Plasma Sci. 2013, 41(3), 613-619.
- 33L. Moravský, M. Klas, E. Machová, K. Pisklová, Š. Matejčík, Open Chem. 2015, 13, 257.
- 34 I. Jõgi, R. Talviste, S. Raud, J. Raud, T. Plank, L. Moravský, M. Klas, Š. Matejčík, Contrib. Plasma Physics 2020, e201900127.
- 35D. Kaniansky, M. Masár, J. Bielčíková, F. Iványi, F. Eisenbeiss, B. Stanislawski, B. Grass, A. Neyer, M. Jöhnck, Anal. Chem. 2000, 72, 3596.
- 36A. Manz, D. J. Harrison, E. M. J. Verpoorte, J. Fettinger, A. Paulus, H. Ludi, H. M. Widmer, J. Chromatogr. A 1992, 593, 253.
- 37D. Kaniansky, M. Masár, R. Bodor, M. Žúborová, M. Ölvecká, M. Johnck, B. Stanislawski, Electrophoresis 2003, 24, 2208.
- 38P. Troška, R. Chudoba, L. Danč, R. Bodor, M. Horčičiak, E. Tesařová, M. Masár, J. Chromatogr. B 2013, 930, 41.
- 39K. Fukui, I. Fujita, K. Kuwata, Mass Spectrosc. 1975, 23, 105.
- 40G.-B. Zhao, M. D. Argyle, M. Radosz, J. Appl. Phys. 2007, 101, 033303.
- 41R. F. Wuerker, L. Schmitz, T. Fukuchi, P. Straus, Chem. Phys. Lett. 1988, 150(6), 443.
- 42T. Tabata, T. Shirai, M. Sataka, H. Kubo, Atom. Data Nucl. Data Tables 2006, 92, 375.
- 43E. J. D. Vredenbregt, W. Boom, R. J. F. van Gerwen, H. C. W. Beijerinck, Chem. Phys. 1990, 145, 267.
- 44P. Schef, A. Derkatch, P. Lundin, Eur. Phys. J. D 2004, 29, 195.
- 45H. Katori, F. Shimizu, Phys. Rev. Lett. 1993, 70, 3545.
- 46 Y. Morabit, R. D. Whalley, E. Robert, M. I. Hasan, J. L. Walsh, Plasma Process Polym. 2019, e1900217. https://doi.org/10.1002/ppap.201900217.
- 47International Conference on Harmonization (ICH), Validation of analytical procedures: text and methodology Q2(R1), Geneva 2005.
- 48H. Xu, S. Wang, M. Shaban, F. Montazersadgh, A. Alkayal, D. Liu, M. G. Kong, B. R. Buckley, F. Iza, Plasma Processes Polym. 2020, 17, 1900162.