• Issue
    Volume 56, Issue 2
    February 2021

Cover Picture

Free Access

Gallium(III) Oxide: Formation of High-Quality Heteroepitaxial β-Ga2O3 Films by Crystal Phase Transition (Crystal Research and Technology 2/2021)

  • First Published: 11 February 2021
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This picture, provided by Min Yang and co-workers (article number 2000149), shows hexagonal shaped ɛ-Ga2O3 islands growing as a film on a c-sapphire substrate. ɛ-Ga2O3 grows well into high-quality films with low surface roughness and low defect density for hexagonal oriented substrates. When the grown ɛ-Ga2O3 film is heat treated under certain conditions, it is completely converted into β-Ga2O3 without changing its morphological properties.

Masthead

Free Access

Masthead: Crystal Research and Technology 2'2021

  • First Published: 11 February 2021

Original Papers

Formation of High-Quality Heteroepitaxial β-Ga2O3 Films by Crystal Phase Transition

  • First Published: 22 December 2020
Description unavailable

Because of its crystallographic properties, β-Ga2O3 film grown by conventional method contains high surface roughness and defect density. However, ɛ-Ga2O3 is easily grown into a high-quality film with a flat surface and low defect density. A new method for producing high-quality β-Ga2O3 films by phase transition of ɛ-Ga2O3 and a method to improve the crystallinity of transformed β-Ga2O3 films are proposed.

Effect of Sodium Sulfate on Nucleation Behavior and the Crystal Morphology of Taurine

  • First Published: 01 December 2020
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Additives are powerful tools to modify the morphology of crystal. The influence of sodium sulfate on taurine's nucleation behavior and morphology was studied, and the intrinsic reason was explored via two Sangwal's models and molecular dynamic simulations in this work. The results obtained in this work could provide theoretical guidance for industrial production.

The Bonding Interactions in Fluorinated Vinylogous Amides: A CF3-Substituted Carbonyl-β-Aminoenone as a Case Study

  • First Published: 22 December 2020
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A new beta-aminoenone is taken as a case study to investigate the intra- and intermolecular interactions in this class of compounds. The Z, s-cis configuration is the only form found both in the crystal and in aprotic solvent. The centre-symmetric dimers constitute a common pattern. The bond order character within the enamine chain is explained with the amide vinylogous concept.

Heteroepitaxial Growth of 1T MoS2 Nanosheets on SnO2 with Synergetic Improvement on Photocatalytic Activity

  • First Published: 29 December 2020
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The epitaxial structures of 1T MoS2 and SnO2 are formed by hydrothermal synthesis. High-resolution transmission electronic microscopy demonstrates the direct evidence of the two configurations formed between MoS2 nanosheets and SnO2 nanoparticles with limit misfits. The photocatalytic activity of MoS2–SnO2 composite constructed by SnO2 of 3–5 nm is highly improved.

Linear-Nonlinear Optical and Quantum Chemical Studies on Quinolinium 4-Aminobenzoate: A Third Order Non-Linear Optical Material for Optoelectronic Applications

  • First Published: 30 December 2020
Description unavailable

Quinolinium 4-aminobenzoate (ABAQ) crystallizes in monoclinic structure with centro-symmetric space group P21. Optical transmission spectrum reveals wide transparency of ABAQ in UV–vis–NIR wavelength region with band gap of 4.73 eV. The laser damage threshold energy density is found to be twelve times that of inorganic KDP. The frequency conversion efficiency of DNBAQ crystal is determined to be 90% of inorganic KDP.

Numerical Study of the Upgraded Hot Zone in Silicon Directional Solidification Process

  • First Published: 06 January 2021
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2D global transient model for G6 GT-style furnace (G6) and upgraded G7 ALD-style furnace (G7) is established and compared. The melt flow intensity is relatively stronger as the furnace upgrades. The over-convex phenomenon of melt–crystal interface is found in the initial stage of G7. G7 shows relatively higher thermal stress and Voronkov ratios due to higher temperature gradient.

A Simple Synthesis Method for Growing Single Crystals of a Copper Coordination Polymer [Cu(C2O4)(4-aminopyridine)2(H2O)]n, and its Theoretical and Physical Properties Studies

  • First Published: 14 January 2021
Description unavailable

Metal–organic polymer-based magnetic systems represent excellent realization of low dimensional magnets. Here, a simple synthetic method is developed for growing large-sized single crystals of a 1D magnetic system, suitable for many future investigations. Detailed theoretical calculations using density functional theory have been undertaken and results are found to be in very good agreement with those from experiments.